Stereochemistry (time in minutes)

  28 Enantiomers (1:05)
 29 Enantiomers, narrated (2:27)*
  30 Diastereomers, narrated (3:33)
  31 Meso Molecules, narrated (4:33)

  32 cis trans Alkenes are Diasteromers, narrated

Copyright 2016. Tap OChem LLC. All rights reserved.

23 Carbocation  Substitution, Hyperconjugation,

   Induction, narrated

All movies included in Tap OChem. Lite version includes those that are starred *

  Substitution Rxns with Alkyl Halides (time in minutes)

  53 SN1 Rxn with R-X, narrated (3:33)
  54 SN1 Rxn with R-X (0:31)
  55 SN1 Rxn with R-X, Rxn Coordinate (0:34)
  56 SN2 Rxn with R-X, Electron Pushing (2:53)*
  57 SN2 Rxn with R-X, Hydroxide Nucleophile (0:21)

  58 SN2 Rxn with R-X, Hydroxide Nucleophile, Rxn Coord. (0:21)

  59 SN2 Rxn with R-X, Methylsulfide Nucleophile (0:35)
  60 SN2 Rxn with R-X, Methylsulfide Nucleophile, Rxn Coord. (0:35)

  61 SN2 Rxn with R-X, Hydroxide Nucleophile, legacy ed. (0:26)*
  62 SN2 Rxn with R-X, Rxn Coordinate, legacy ed. (0:22)*
  63 SN2 Rxn with R-X, Stereochemistry (0:27)*
  64 SN2 Rxn with R-X, Molecular Orbitals (0:25)

MOVIE LIST

  Carbonyl Chemistry (time in minutes)

  97 Hydration, Basic Conditions, narrated (1:59)
  98 Hydration, Acid Conditions, narrated (3:19)
  99 Cyanohydrin Formation, HCN Addition (9:21)
 100 Keto-Enol Tautormerization, Base Conditions (0:24)
 101Keto-Enol Tautormerization, Acid Conditions (0:34)
 102 Alpha Halogenation, Acid Conditions (0:50)
 103 Carbonyl and gem-diol Equilibrium, narrated (6:04)

 104 Acetal and Hemiacetal Formation, narrated (6:07)

   Aromaticity and Stability (time in minutes)

  13 Benzene and Stability, narrated (4:03)
  14 Benzene and Huckel, narrated (7:43)

  Benzene Stability and Aromaticity (time in minutes)

  87 Benzene and Stability, narrated (4:03)

  88 Benzene and Huckel, narrated (7:43)

  Substitution Rxns with Alcohols (time in minutes)

  49 SN1 Rxn with R-OH (0:35)
  50 SN1 Rxn with R-OH, Rxn Coordinate (0:31)
  51 SN2 Rxn with R-OH (0:50)
  52 SN2 Rxn with R-OH, Rxn Coordinate (0:45)

  Elimination Rxns with Alkyl Halides (time in minutes)

  41 E1 Reaction with R-X, electron pushing, narrated (3:59)
  42 E1 Rxn with R-X (1:09)
  43 E1 Rxn with R-X, Rxn Coordinate (0:46)
  44 E2 Rxn with R-X, electron pushing, narrated (5:05)*
  45 E2 Rxn with R-X (0:41)*
  46 E2 Rxn with R-X, Rxn Coordinate (0:48)*
  47 E2 Rxn with R-X, Regiochemistry 1, narrated (3:59)
  48 E2 Rxn with R-X, Regiochemistry 2, narrated (4:00)

42 E1 Rxn with RX

35 Dienes and Stability, narrated

  Cyclohexane Conformational Analysis (time in minutes)

  15 Drawing Cyclohexane's Chair Conformation (4:35)

  16  Cyclohexane Conformations (0:21)
  17 Cyclohexane Conformations, narrated (1:21)
  18  Cyclohexane Energy Diagram (0:40)
  19 Cyclohexane Energy Diagram, narrated (1:13)
  20 Methylcyclohexane (0:44)

  21 Methylcyclohexane, narrated (3:14)

  Reactions of Epoxides (time in minutes)

  67 Nucleophilic Ring Opening (0:31)*
  68  Acid-Catalyzed Ring Opening (0:29)

  Radical Stability (time in minutes)

  24 Radical Substitution, Hyperconjugation (0:50)
  25 Radical Substitution, Hyperconjugation, narrated (1:35)

  Molecules (time in minutes)

 105 Methane (0:20)*
 106 Ethane (0:20)
 107 Ethanes in a Box (0:25)
 108 Propane (0:20)*
 109 Ethene (0:20)
 110 Ethene, with p-orbitals (0:20)*
 111 Ethyne (0:20)
 112 Ethyne, with p-orbitals (0:20)*
 113 Allene (0:20)
 114 Allene, with p-orbitals (0:20)

 115 1,3-Butadiene (0:20)

 116 1,3-Butadiene, with p-orbitals (0:24)
 117 Formaldehyde (0:24)
 118 Formaldehyde, with p-orbitals (0:24)
 119 N,N-Dimethylformamide (0:21)

 120 N,N-Dimethylformamide Rotation and Orbitals (1:29)
 121 Cyclopropane (0:20)

 122 Ethylene Oxide (0:20)

 123 Cyclobutane (0:20)
 124 Cyclobutadiene (0:24)
 125 Cyclopentane (0:20)*
 126 Cyclopentadienyl Anion (0:24)
 127 Benzene (0:20)
 128 Benzene, with p-orbital array (0:21)
 129 Cycloheptatriene (0:22)
 130 Cycloheptatrienyl Cation (0:24)
 131 Cyclooctatetraene (0:30)
 132 tert-Butyl Cation (0:20)
 133 tert-Butyl Radical (0:20)*
 134 Allyl Cation (0:24)
 135 Allyl Radical (0.24)*
 136 Benzyl Cation (0:21)
 137 Cyclopentadienyl Anion (0:24)
 138 Cycloheptatrienyl Cation (0:24)

33 Alkene Stability Part 1

  Diene Stability (time in minutes)

  35 Dienes and Stability, narrated (6:32)
  36 Butadiene Rotation (1:03)
  37 Butadiene Rotation, narrated (2:59)

  Alkene Reactions (time in minutes)

  70 Hydrogenation (0:48)*
  71 Bromination (0:35)*
  72 Br-OH Addition, Halohydrin Formation (0:46)
  73  H-X Addition (0:29)
  74  Epoxidation (0:27)
  75 Hydroboration-Oxidation, narrated (7:44)

56 SN2 Rxn with R-X, Electron Pushing

  Free Radical Halogenation (time in minutes)

  69 Radical Chlorination of Methane, narrated (4:49)

  Valence Bond Theory (time in minutes)
   1 sp3 hybridization (1:03)
   2 sp3 hybridization, narrated (1:05)*
   3 sp2 hybridization (1:09)
   4 sp2 hybridization, narrated (1:09)*
   5 sp hybridization (1:14)
   6 sp hybridization, narrated (1:14)*

  Diene Chemistry (time in minutes)

  76 Diels-Alder 1 Fundamentals, narrated (4:04)

  77 Diels-Alder 2 Diene and Dienophile Substituents, narrated (3:46)

  78 Diels-Alder 3 Stereochemistry, Dienophiles, Endo Rule,

       narrated (3:34)

  79 Diels-Alder I (0:46)*
  80 Diels-Alder II Endo Rule (0:24)

29 Enantiomers, narrated

  Reactions of Alkynes: Alkene Formation (time in minutes)

  85 Trans Alkenes from Alkynes (0:40)
  86 Trans Alkenes from Alkynes, narrated (1:49)*

Tap OChem

  Benzene Reactions (time in minutes)

  89 Benzene Bromination (0:37)*
  90 Benzene Bromination, Rxn Coordinate (0:33)*
  91 Benzene Sulfonation (0:44)
  92 Benzene Sulfonation, Rxn Coordinate (0:35)
  93 Benzene Nitration (0:44)
  94 Benzene Nitration, Rxn Coordinate (0:44)
  95 Friedel-Crafts Alkylation (0:40)
  96 Friedel-Crafts Acylation (0:36)

34 Alkene Stability Part 2

  Formation of Epoxides (time in minutes)

  65 Epoxides from Halohydrins (0:27)*
  66 Epoxidation of Alkenes (0:27)

  Alkane Conformational Analysis (time in minutes)
    7 Chemical Representations (1:28)*
    8 Chemical Representations, narrated (1:24)
    9 Ethane Rotation (0:44)*
  10 Ethane Rotation, narrated (1:17)
  11 Butane Rotation (0:21)
  12 Butane Rotation, narrated (1:23)*

  Carbocation Stability (time in minutes)

  22 Carbocation  Substitution, Hyperconjugation, Induction (1:00)
  23 Carbocation  Substitution, Hyperconjugation, Induction, 

       narrated (1:57)*

  Alkynyl Chemistry (time in minutes)

  81 Alkyne Alkylation (0:24)*
  82 Hydridization and Stability (0:56)
  83 Hydridization and Stability, narrated (1:52)
  84 Cis Alkenes from Alkynes (0:44)

  Elimination Rxns with Alcohols (time in minutes)

  38 E1 Rxn with R-OH (0:48)
  39 E1 Rxn with R-OH, Rxn Coordinate (0:48)
  40 E2 Rxn with R-OH (0:40)

  Carbanion Stability (time in minutes)

  26 Carbanion Hydridization and Stability (0:56)
  27 Carbanion Hydridization and Stability, narrated (1:52)

  Alkene Stability (time in minutes)

  33 Alkene Stability Part 1, narrated (5:37)
  34 Alkene Stability Part 2, narrated (5:30)